댓글 0건 조회 442회 작성일 2019-07-24 11:28
Nozzle clogging during continuous casting of Ti-ULC (Ultra Low C) steel was investigated by inspections of plant-used SENs and laboratory scale experiments using a rotating finger method. Various Al/Ti ratios in the steel and different kinds of nozzles (with or without CaO) were employed. Clog deposits found in the used SENs were composed of complicated oxide (CaO–Al2O3–TiOx-…), Fe drops and chunks. Increasing Ti concentration increased amount of the deposit the metallic deposits. In the laboratory scale experiments, increasing Al/Ti ratios was effective to suppress the formation of the deposit and the oxidation loss of Ti in the steel. When a refractory without CaO was used, increasing Al/Ti ratio decreased the portion of Ti oxide in the deposit. Almost no Fe drops were observed, except for a thin layer of Fe on surface of the oxide deposit. When CaO-lined refractory was used, many numbers of Fe drops were found inside the deposit. Increasing Al/Ti ratio lowered Ti peak in the oxide deposit. The present results lend a strong support that Ti-ULC steel is oxidized by CO gas from nozzle refractory, forming FetO-containing liquid oxide and solid alumina. The liquid oxide is reduced to leave Fe drops and Al2O3–TiOx layer. If CaO presents in the nozzle, then a complicated oxide of CaO–Al2O3–TiOx forms, as was found in the SEN from the practical operation.
KEY WORDS: Ti-ULC steel casting; nozzle clogging; Al/Ti ratio; FetO–Al2O3–TiOx; nozzle refractory.
- 이전글[CSL] Prof.Youn-Bae Kang:Dissolution kinetics of alumina in molten CaO–Al2O3–FetO– MgO–SiO2 oxide representing the RH slag in steelmaking process 20.06.10
- 다음글[CSL] Prof. Youn-Bae Kang: ISIJ International, Vol. 58(2018), No. 7, pp.1257-1266 18.08.31
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